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VPNs no, but proxies yes. Since it works with proxies too, you can search for a free Russian proxy.
If that is too much work, buy the games from plati.ru.
Buying in the Russian store with your main account is not a good choice. It's better to use a 2nd account and then gift/trade the games to your main account.
If you don't wanna create a 2nd account, just buy from plati.ru.
Steam ALWAYS detects attempts to buy from another store frontend via VPN. That's known, tried and true. And invariably results in a locked account, a Steam Support Ticked, questions and a royal pain in the ass to get full access restored.
Avoid.
300 RUB Yandex.Money = 11.9 USD PayPal
After payment, I will send the Money to your Yandex.Money account.
-FAQ-
Yandex.Money:
Yandex.Money is a Russian payment system which can be used to buy games from the Russian Steam store or almost any Russian game site such as plati.ru.
How to get a Yandex.Money account:
How to buy games from the Russian Steam store with Yandex.Money:
How to buy games from plati.ru: